Here's a couple quotes from some of my previous responses to low pH levels. Hopefully, they will help you learn a little about pH in aquariums.
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Assuming that your test kits are all accurate, my guess would still be that it is from excess CO2 if your not adding any chemicals besides kalk, although getting more fresh air into your skimmer should have helped. Have you read this article? Chemistry and the Aquarium IMO, it is the best article on the web dealing with pH in aquariums.
Take a bucket of water out of your aquarium and place it outside for a few hours with a powerhead or air pump circulation the water and rippling the surface. This will drive off most of the CO2 in the water. After you do that for a while, retest the pH of the bucket of water and see what you get. If the pH in the bucket is higher, you still have excess CO2 in your tank's water.
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You should be using the unscented baking soda to raise your alkalinity levels if your levels are low. Doing this will help buffer/raise your pH. Don't just keep adding ANY chemicals to raise your pH. If you alkalinity levels are in the optimum range and your pH is still low, more than likely you are either adding pH lowering chemicals into your tank or your tank has a high carbon dioxide level (very common) in it (usually because your house has high levels in the air). If you add baking soda, washing soda, baked baking soda, or any other pH buffer/raising chemical without knowing where your alkalinity,calcium, and magnesium levels are you are asking for trouble.
BTW - I've had tanks remain in the 7.7-8.0 range and everything thrived. In fact, during winter months it was common for my pH to drop to around 7.65 in the morning. Just remember that stability is just as important as optimum readings.
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Baking soda, and most other pH adjusting additives, help to raise the pH by raising the alkalinity. I NEVER add any chemicals aimed specifically at adjusting the pH. 90%+ of the time if pH is low, some other water parameter is off, something is being added to the tank that is lowering the pH, or their is a high carbon dioxide level in the tank.
BTW - pH may fluctuate by as much as 0.25 throughout the day. Generally, it will be the lowest right before the lights come on and highest when the lights shut off.